Name: Name:1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane
Brand: Angene
SKU: AG0036P6
Rating: 90 (10 reviews)

1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane

CAS No.:

97739-46-3

Catalog Number:

AG0036P6

Molecular Formula:

C16H21O3P

Molecular Weight:

292.3099

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Product Description

Catalog Number:

AG0036P6

Chemical Name:

1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane

CAS Number:

97739-46-3

Molecular Formula:

C16H21O3P

Molecular Weight:

292.3099

MDL Number:

MFCD10567051

IUPAC Name:

1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane

InChI:

InChI=1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3

InChI Key:

AVVSJWUWBATQBX-UHFFFAOYSA-N

SMILES:

CC12CC3(C)OC(P2c2ccccc2)(CC(O1)(O3)C)C

Properties

Complexity:

407

Compound Is Canonicalized:

Yes

Covalently-Bonded Unit Count:

Defined Atom Stereocenter Count:

Defined Bond Stereocenter Count:

Exact Mass:

292.123g/mol

Formal Charge:

Heavy Atom Count:

Hydrogen Bond Acceptor Count:

Hydrogen Bond Donor Count:

Isotope Atom Count:

Molecular Weight:

292.315g/mol

Monoisotopic Mass:

292.123g/mol

Rotatable Bond Count:

Topological Polar Surface Area:

27.7A^2

Undefined Atom Stereocenter Count:

Undefined Bond Stereocenter Count:

XLogP3:

2.5

Literature

Title	Journal
Reversed-polarity synthesis of diaryl ketones via palladium-catalyzed cross-coupling of acylsilanes.	Journal of the American Chemical Society 20111214
Synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones via intramolecular cyclocarbonylation reactions using PdI(2)/Cytop 292 as the catalytic system.	The Journal of organic chemistry 20100917
Access to flavones via a microwave-assisted, one-pot Sonogashira-carbonylation-annulation reaction.	Organic letters 20090806
Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium(I) hydroformylation catalysts.	Dalton transactions (Cambridge, England : 2003) 20050321
Palladium complexes of 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane: synthesis, crystal structure and use in the Suzuki and Sonogashira reactions and the alpha-arylation of ketones.	The Journal of organic chemistry 20040723
Novel class of tertiary phosphine ligands based on a phospha-adamantane framework and use in the Suzuki cross-coupling reactions of aryl halides under mild conditions.	Organic letters 20030320