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TROPONE

CAS No.:
539-80-0
Catalog Number:
AG003V9B
Molecular Formula:
Molecular Weight:
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Product Description
Catalog Number:
AG003V9B
Chemical Name:
TROPONE
CAS Number:
539-80-0
MDL Number:
MFCD00014331
IUPAC Name:
cyclohepta-2,4,6-trien-1-one
InChI:
InChI=1S/C7H6O/c8-7-5-3-1-2-4-6-7/h1-6H
InChI Key:
QVWDCTQRORVHHT-UHFFFAOYSA-N
EC Number:
208-725-6
UNII:
CO48X7SUFH
Properties
Complexity:
155  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
106.042g/mol
Formal Charge:
0
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
106.124g/mol
Monoisotopic Mass:
106.042g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
17.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.6  
Literature
Title Journal
Experimental verification of the homoaromaticity of 1,3,5-cycloheptatriene and evaluation of the aromaticity of tropone and the tropylium cation by use of the dimethyldihydropyrene probe. Journal of the American Chemical Society 20121010
The isolation of a new S-methyl benzothioate compound from a marine-derived Streptomyces sp. Journal of biomedicine & biotechnology 20120101
Unusual catalytic effect of the two-dimensional molecular space with regular triphenylphosphine groups. Langmuir : the ACS journal of surfaces and colloids 20111004
Highly selective synthesis of pyrazole and spiropyrazoline phosphonates via base-assisted reaction of the Bestmann-Ohira reagent with enones. The Journal of organic chemistry 20110603
Activation of sulfonate ester based matrix metalloproteinase proinhibitors by hydrogen peroxide. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20110201
The catalytic role of uranyl in formation of polycatechol complexes. Chemistry Central journal 20110101
Identification of the antibacterial compound produced by the marine epiphytic bacterium Pseudovibrio sp. D323 and related sponge-associated bacteria. Marine drugs 20110101
Total synthesis of pareitropone via radical anion coupling. Organic letters 20100903
Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing a ferrocenyl group at 5-position. Dalton transactions (Cambridge, England : 2003) 20100307
Identification and biosynthesis of tropone derivatives and sulfur volatiles produced by bacteria of the marine Roseobacter clade. Organic & biomolecular chemistry 20100107
On the chiroptical behavior of conjugated multichromophoric compounds of a new pseudoaromatic class: bicolchicides and biisocolchicides. PloS one 20100101
Benzo[cd]azulene skeleton: azulene, heptafulvene, and tropone derivatives. Organic letters 20091203
Lewis acid catalyzed inverse-electron-demand Diels-Alder reaction of tropones. Journal of the American Chemical Society 20091125
Access to a welwitindolinone core using sequential cycloadditions. Organic letters 20090820
Iron-catalyzed cross-aldol reactions of ortho-diketones and methyl ketones. Chemical communications (Cambridge, England) 20090614
Pernambucone, a new tropone derivative from Croton argyroglossum. Die Pharmazie 20090501
Tumor-specific cytotoxicity and type of cell death induced by benzo[b]cyclohept[e][1,4]oxazine and 2-aminotropone derivatives. Anticancer research 20090401
Novel 3,4-diazabenzotropone compounds (2,3-benzodiazepin-5-ones): synthesis, unique reactivity, and biological evaluation. Organic letters 20090319
Ring-expansion protocol: preparation of synthetically versatile dihydrotropones. The Journal of organic chemistry 20090116
Asymmetric synthesis of bicyclo[4.3.1]decadienes and bicyclo[3.3.2]decadienes via [6 + 3] trimethylenemethane cycloaddition with tropones. Journal of the American Chemical Society 20081112
Further studies of the norditerpene (+)-harringtonolide isolated from Cephalotaxus harringtonia var. drupacea: absolute configuration, cytotoxic and antifungal activities. Planta medica 20080601
Crototropone, a new tropone derivative from Croton zehntneri. Fitoterapia 20080401
Computational studies of the tropone natural products, thiotropocin, tropodithietic acid, and troposulfenin. Significance of thiocarbonyl-enol tautomerism. The Journal of organic chemistry 20080104
Synthesis of 4-aminotropones from [(sulfinyl or sulfonyl)methyl]-substituted p-quinamines. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Crystal structures of 2-aminotropone, n,n'-di(tropon-2-yl)piperazine, and 5-(4-ethoxyphenylazo)tropolone. Journal of oleo science 20080101
Model studies toward the synthesis of the bioactive diterpenoid, harringtonolide. Organic & biomolecular chemistry 20070821
A new access to dihydrotropones through ring expansion of spirocyclohexadienones: synthesis and mechanism. The Journal of organic chemistry 20070817
Quantum chemical study of the thermal decomposition of o-quinone methide (6-methylene-2,4-cyclohexadien-1-one). The journal of physical chemistry. A 20070816
An N-heterocyclic carbene-catalyzed [8 + 3] annulation of tropone and enals via homoenolate. The Journal of organic chemistry 20061110
Relationship between electronic structure and cytotoxic activity of tropolones. In vivo (Athens, Greece) 20060101
A phosphine-catalyzed [3+6] annulation reaction of modified allylic compounds and tropone. Organic letters 20050512
Ring expansion of sulfur substituted p-quinamines: regiospecific synthesis of 4-aminotropones. Chemical communications (Cambridge, England) 20050227
Kinetic stabilization of the o-quinoidal 3,4-benzotropone system. Organic & biomolecular chemistry 20040907
Pi-extended o-quinoidal tropone derivatives: experimental and theoretical studies of naphtho[2,3-c]tropone and anthro[2,3-c]tropone. Organic & biomolecular chemistry 20040407
Comparison of tropane alkaloid spectra between Datura innoxia grown in Egypt and Bulgaria. Zeitschrift fur Naturforschung. C, Journal of biosciences 20040101
New syntheses and chemistry of hexafluorotropone. The Journal of organic chemistry 20030516
SnCl4-catalyzed reaction of o-benzoquinones and aryl acetylenes: an unprecedented one-pot synthesis of tropone derivatives. The Journal of organic chemistry 20021018
Application of Lewis acid catalyzed tropone [6+4] cycloadditions to the synthesis of the core of CP-225,917. Organic letters 20011227
Properties