Home Other Building Blocks Silane,acetyltrimethyl-

Silane,acetyltrimethyl-

CAS No.:
13411-48-8
Catalog Number:
AG007MK4
Molecular Formula:
C5H12OSi
Molecular Weight:
116.2337
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Product Description
Catalog Number:
AG007MK4
Chemical Name:
Silane,acetyltrimethyl-
CAS Number:
13411-48-8
Molecular Formula:
C5H12OSi
Molecular Weight:
116.2337
MDL Number:
MFCD00134244
IUPAC Name:
1-trimethylsilylethanone
InChI:
InChI=1S/C5H12OSi/c1-5(6)7(2,3)4/h1-4H3
InChI Key:
REDWSDBFBCDPNI-UHFFFAOYSA-N
SMILES:
CC(=O)[Si](C)(C)C
Properties
Complexity:
80.6  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
116.066g/mol
Formal Charge:
0
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
116.235g/mol
Monoisotopic Mass:
116.066g/mol
Rotatable Bond Count:
1  
Topological Polar Surface Area:
17.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Highly enantioselective reduction of 4-(trimethylsilyl)-3-butyn-2-one to enantiopure (R)-4-(trimethylsilyl)-3-butyn-2-ol using a novel strain Acetobacter sp. CCTCC M209061. Bioresource technology 20091201
Using a water-immiscible ionic liquid to improve asymmetric reduction of 4-(trimethylsilyl)-3-butyn-2-one catalyzed by immobilized Candida parapsilosis CCTCC M203011 cells. BMC biotechnology 20090101
An efficient de novo synthesis of partially reduced phenanthrenes through C-C insertion. The Journal of organic chemistry 20070914
Acetyltrimethylsilane: a novel reagent for the transformation of 2H-pyran-2-ones to unsymmetrical biaryls. The Journal of organic chemistry 20060120
Theoretical and experimental investigation of the basicity of phosphino(silyl)carbenes. The Journal of organic chemistry 20050708
Synthesis of (R)-2-trimethylsilyl-2-hydroxyl-ethylcyanide catalyzed with (R)-oxynitrilase from loquat seed meal. Biotechnology letters 20050101
Enzymatic enantioselective transcyanation of silicon-containing aliphatic ketone with (S)-hydroxynitrile lyase from Manihot esculenta. Applied microbiology and biotechnology 20041101
(R)-oxynitrilase-catalysed synthesis of chiral silicon-containing aliphatic (R)-ketone-cyanohydrins. Biotechnology letters 20030201
[Asymmetric microbial reduction of organosilyl ketone with immobilized Saccharomyces cerevisiae cells]. Wei sheng wu xue bao = Acta microbiologica Sinica 20020801
Acetyltrimethylsilane, trifluoromethyltrimethylsilane, and prenyl esters: a three-component system for the synthesis of gem-difluoroanalogues of monoterpenes. The Journal of organic chemistry 20010615
Properties