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Diallyl carbonate

CAS No.:
15022-08-9
Catalog Number:
AG00ABEJ
Molecular Formula:
C7H10O3
Molecular Weight:
142.1525
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$32
- +
5g
95%
In Stock USA
United States
$94
- +
25g
95%
In Stock USA
United States
$325
- +
Product Description
Catalog Number:
AG00ABEJ
Chemical Name:
Diallyl carbonate
CAS Number:
15022-08-9
Molecular Formula:
C7H10O3
Molecular Weight:
142.1525
MDL Number:
MFCD00008645
IUPAC Name:
bis(prop-2-enyl) carbonate
InChI:
InChI=1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2
InChI Key:
JKJWYKGYGWOAHT-UHFFFAOYSA-N
SMILES:
C=CCOC(=O)OCC=C
EC Number:
239-106-9
NSC Number:
19177
Properties
Complexity:
115  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
142.063g/mol
Formal Charge:
0
Heavy Atom Count:
10  
Hydrogen Bond Acceptor Count:
3  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
142.154g/mol
Monoisotopic Mass:
142.063g/mol
Rotatable Bond Count:
6  
Topological Polar Surface Area:
35.5A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.8  
Literature
Title Journal
Pd-catalyzed reaction of allyl carbonate with polyols: the role of CO2 in transesterification versus etherification of glycerol. Chemistry (Weinheim an der Bergstrasse, Germany) 20120227
Contemporaneous dual catalysis: chemoselective cross-coupling of catalytic vanadium-allenoate and π-allylpalladium intermediates. Journal of the American Chemical Society 20110817
Diallyl 5-[(4-hexyl-oxyphen-yl)imino-meth-yl]-m-phenyl-ene dicarbonate. Acta crystallographica. Section E, Structure reports online 20091101
Allyl 4-hydroxy-phenyl carbonate. Acta crystallographica. Section E, Structure reports online 20090701
Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis. Journal of the American Chemical Society 20090401
Enzymatic desymmetrization of prochiral 2-substituted-1,3-diamines: preparation of valuable nitrogenated compounds. The Journal of organic chemistry 20090320
Synthesis, structure, electrochemistry, and cytotoxic properties of ferrocenyl ester derivatives. Metal-based drugs 20090101
First desymmetrization of 1,3-propanediamine derivatives in organic solvent. Development of a new route for the preparation of optically active amines. Organic letters 20071011
Preparation of cyclic 2',3'-carbamate derivatives of erythromycin macrolide antibiotics. Bioorganic & medicinal chemistry 20070501
Examination of the effects of poly(N-vinylpyrrolidinone) hydrogels in direct and indirect contact with cells. Biomaterials 20060501
Total synthesis of (+/-)-jiadifenin and studies directed to understanding its SAR: probing mechanistic and stereochemical issues in palladium-mediated allylation of enolate-like structures. Journal of the American Chemical Society 20060125
Mechanism of formation of organic carbonates from aliphatic alcohols and carbon dioxide under mild conditions promoted by carbodiimides. DFT calculation and experimental study. The Journal of organic chemistry 20050805
From hydrocolloids to high specific surface area porous supports for catalysis. Biomacromolecules 20050101
A one-pot procedure for the regiocontrolled synthesis of allyltriazoles via the Pd-Cu bimetallic catalyzed three-component coupling reaction of nonactivated terminal alkynes, allyl carbonate, and trimethylsilyl azide. The Journal of organic chemistry 20040402
5H-oxazol-4-ones as building blocks for asymmetric synthesis of alpha-hydroxycarboxylic acid derivatives. Journal of the American Chemical Society 20040225
Novel synthesis of 3-azabicyclo[3.1.0]hexanes by unusual palladium(0)-catalyzed cyclopropanation of allenenes. Organic letters 20031211
Synthesis of triazoles from nonactivated terminal alkynes via the three-component coupling reaction using a Pd(0)-Cu(I) bimetallic catalyst. Journal of the American Chemical Society 20030702
On the regiochemistry of nucleophilic attack on 2-halo pi-allyl complexes. 4. The effect of silver acetate and nucleophile concentrations in competitive nucleophilic attack with malonate and phenoxide nucleophiles. The Journal of organic chemistry 20030516
Catalytic asymmetric synthesis of optically active atropisomeric anilides through enantioselective N-allylation with chiral Pd-tol-BINAP catalyst. The Journal of organic chemistry 20021129
Novel synthetic route to allyl cyanamides: palladium-catalyzed coupling of isocyanides, allyl carbonate, and trimethylsilyl azide. Journal of the American Chemical Society 20010926
Properties